| 1 |  Rui Alberto Faria da Costa (POR) | Caisse d'Epargne | 3:27:21 |
| 2 |  Joan Sebastian Horrach Rippoll (ESP) | Team Katusha | 0:00:02 |
| 3 | Jose Ivan Gutierrez Palacios (ESP) | Caisse d'Epargne | 0:00:07 |
| 4 | Aitor Perez Arrieta (ESP) | Footon - Servetto | mt |
| 5 | José Joaquin Rojas Gil (ESP) | Caisse d'Epargne | mt |
| 6 |  Kim Kirchen (LUX) | Team Katusha | mt |
| 7 | Beñat Intxausti Elorriaga (ESP) | Euskaltel - Euskadi | mt |
| 8 | Manuel Vazquez Hueso (ESP) | Andalucía - Cajasur | mt |
| 9 | Rafael Valls Ferri (ESP) | Footon - Servetto | mt |
| 10 |  Eduard Vorganov (RUS) | Team Katusha | mt |
| 11 |  Jelle Vanendert (BEL) | Omega Pharma - Lotto | mt |
| 12 | Rubén Plaza Molina (ESP) | Caisse d'Epargne | mt |
| 13 | Dries Devenyns (BEL) | Quick Step | mt |
| 14 |  Christian Knees (GER) | Team Milram | mt |
| 15 | Jurgen Van Den Broeck (BEL) | Omega Pharma - Lotto | mt |
| 16 |  Fabio Felline (ITA) | Footon - Servetto | mt |
| 17 | Eros Capecchi (ITA) | Footon - Servetto | mt |
| 18 | Maxime Vantomme (BEL) | Team Katusha | mt |
| 19 | Maxime Monfort (BEL) | Team HTC - Columbia | mt |
| 20 | Mikel Landa Meana (ESP) | Orbea | mt |
| 21 | Amets Txurruka Ansola (ESP) | Euskaltel - Euskadi | mt |
| 22 | Fränk Schleck (LUX) | Saxo Bank | mt |
| 23 | Alexandre Botcharov (RUS) | Team Katusha | mt |
| 24 |  Laurens Ten Dam (NED) | Rabobank | mt |
| 25 |  Matthias Brändle (AUT) | Footon - Servetto | mt |
| 26 | Jens Voigt (GER) | Saxo Bank | mt |
| 27 | Markus Eibegger (AUT) | Footon - Servetto | mt |
| 28 | Rodrigo García Rena (ESP) | Xacobeo - Galicia | mt |
| 29 |  Jean-Christophe Péraud (FRA) | Omega Pharma - Lotto | mt |
| 30 | Alexandr Kolobnev (RUS) | Team Katusha | mt |
| 31 | Linus Gerdemann (GER) | Team Milram | mt |
| 32 | Angel Madrazo Ruiz (ESP) | Caisse d'Epargne | mt |
| 33 | Egor Silin (RUS) | Team Katusha | mt |
| 34 | Francis De Greef (BEL) | Omega Pharma - Lotto | 0:00:17 |
| 35 | Markus Fothen (GER) | Team Milram | 0:00:21 |
| 36 |  Rein Taaramäe (EST) | Cofidis, le Crédit en Ligne | 0:01:00 |
| 37 | Vicente Reynès Mimo (ESP) | Team HTC - Columbia | 0:01:07 |
| 38 | Juan Jose Oroz Ugalde (ESP) | Euskaltel - Euskadi | 0:01:20 |
| 39 | Mikel Nieve Iturralde (ESP) | Euskaltel - Euskadi | mt |
| 40 | David Gutierrez Palacios (ESP) | Footon - Servetto | mt |
| 41 | Daniel Moreno Fernández (ESP) | Omega Pharma - Lotto | 0:01:53 |
| 42 | Dario Cataldo (ITA) | Quick Step | 0:02:00 |
| 43 | Rikke Dijkxhoorn (NED) | Van Vliet - Ebh - Elshof | 0:02:29 |
| 44 | Carlos Torrent Tarres (ESP) | Equipo Nacional de España | 0:02:30 |
| 45 | Tassilo Fricke (GER) | Team Netapp | mt |
| 46 | Raul Santamarta Valvuena (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 47 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | 0:02:33 |
| 48 | Ángel Vicioso Arcos (ESP) | Andalucía - Cajasur | mt |
| 49 | Fabian Wegmann (GER) | Team Milram | mt |
| 50 | Johannes Fröhlinger (GER) | Team Milram | mt |
| 51 | Bram Tankink (NED) | Rabobank | mt |
| 52 | Javier Moreno Bazan (ESP) | Andalucía - Cajasur | mt |
| 53 |  Gregory Brenes Obando (CRC) | Burgos 2016 - Castilla y Leon | 0:03:00 |
| 54 | Paul Voss (GER) | Team Milram | 0:03:25 |
| 55 | Arnold Jeannesson (FRA) | Caisse d'Epargne | mt |
| 56 | Igor Antón Hernandez (ESP) | Euskaltel - Euskadi | mt |
| 57 | Serafín Martínez Acevedo (ESP) | Xacobeo - Galicia | mt |
| 58 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 59 | Romain Zingle (BEL) | Cofidis, le Crédit en Ligne | mt |
| 60 | Giampaolo Cheula (ITA) | Footon - Servetto | mt |
| 61 | Sylvain Chavanel (FRA) | Quick Step | 0:04:30 |
| 62 | Jérôme Pineau (FRA) | Quick Step | mt |
| 63 | Davide Malacarne (ITA) | Quick Step | mt |
| 64 | Pascual Orengo Lopez (ESP) | Burgos 2016 - Castilla y Leon | 0:04:54 |
| 65 | Vladimir Karpets (RUS) | Team Katusha | mt |
| 66 | Antonio Piedra Perez (ESP) | Andalucía - Cajasur | mt |
| 67 |  Rasmus Poulsen Guldhammer (DEN) | Team HTC - Columbia | mt |
| 68 | Chris Anker Sørensen (DEN) | Saxo Bank | mt |
| 69 | José Carlos Lara Arjonilla (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 70 | Bas Stamsnijder (NED) | Van Vliet - Ebh - Elshof | mt |
| 71 | David Francisco Delgado (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 72 | David Arroyo Duran (ESP) | Caisse d'Epargne | 0:06:01 |
| 73 | Sergio Escobar Roure (ESP) | Equipo Nacional de España | mt |
| 74 | Xabier Zandio Echaide (ESP) | Caisse d'Epargne | mt |
| 75 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | 0:08:02 |
| 76 | Ronan Van Zandbeek (NED) | Skil - Shimano | 0:08:19 |
| 77 |  Charles Wegelius (GBR) | Omega Pharma - Lotto | 0:08:29 |
| 78 | Jan Bakelants (BEL) | Omega Pharma - Lotto | 0:08:30 |
